I'm getting pretty stoked for the next Bond movie, Spectre. I bought the iTunes collection over Christmas when they dropped it to $99. Now it's a little more, but still a great deal for 23 classic movies.
One of my favorite tech writers/podcasters did a podcast episode on each movie a while back. I'm working my way through watching each movie and then listening to the corresponding podcast. If you're interested in something like this then you can check out the podcast collection here.
If you're not sure how you would download each podcast individually, check out Huffduffer. A great service that let's you create your own podcast feed that you can add anything to.